Investigation of hydration mechanisms of alpha and beta hemihydrate …

Gypsum-based binders are generally based on the reaction between calcium sulfate hemihydrate (HH) and water to form calcium sulfate dihydrate (DH). Often gypsum can be used as a raw material to obtain hemihydrate. In this study, the obtained alpha hemihydrate consists of large crystals that have more or less lattice defects according …

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What is the Difference Between Alpha and Beta Hemihydrate

The difference between alpha and beta hemihydrate is their solubility. Alpha hemihydrate is more soluble and sets faster than the beta form. EXPLORE. Travel & Tour; Education; Language; ... The process of converting gypsum into alpha hemihydrate involves heating gypsum at a specific temperature to remove water molecules, resulting …

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Anhydrite and gypsum

Learn about the formation, stability and depositional features of anhydrite and gypsum, the two most abundant minerals of ancient marine evaporite deposits. Explore …

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α or β?-hemihydrates transformed from dihydrate calcium sulfate …

1. Introduction. Calcium sulfate is the subject of much research due to its wide scope and large-scale of industrial applications [1], [2], [3].It occurs in nature mainly in form of three different phases distinguished by the content of crystal water: dihydrate (DH, CaSO 4 ·2H 2 O), hemihydrate (HH, CaSO 4 ·0.5H 2 O), and anhydrite (AH, CaSO …

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Gypsum vs. Anhydrite: What's the Difference?

Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, whereas anhydrite is its anhydrous form, lacking water in its structure. Key Differences Gypsum, a widely used mineral, is known for its softness and is composed of calcium sulfate dihydrate.

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Hydration characteristics and mechanism analysis of β …

Three main commercial beta calcium sulfate hemihydrate from natural gypsum, phosphogypsum and flue gas desulphurization gypsum, represented as NH, PH, and DH, supplied by Chengdu Hongtai High Strength Gypsum Co. Ltd, Sichuan Longmang Gypsum Industry Development Co. Ltd and Chengdu Landing Environmental Protection …

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What is the Difference Between Gypsum and Plaster of Paris

The difference between Gypsum and plaster of Paris is their water content. Gypsum has two water molecules per calcium sulfate molecule, whereas plaster of Paris is its dehydrated form with only half a water molecule. ... The resulting product is plaster of Paris, with the chemical formula CaSO4 • ½ H 2 O (calcium sulfate hemihydrate). This ...

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Gypsum vs Anhydrite

Gypsum is softer, whereas anhydrite is a hard crystal. The hardness rating of gypsum is about 2, while If we look at its hardness rating of anhydrite, then it is 3.5. The density of gypsum is about 2.33g/cc, whereas the density of anhydrite is 3.2g/cc. Gypsum has a monoclinic structural form, while anhydrite has an orthorhombic structural form.

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Calcium sulfate

Drierite (anhydrous) Gypsum Plaster of Paris. Properties Chemical formula. CaSO 4: Molar mass: 136.14 g/mol (anhydrous) 145.15 g/mol (hemihydrate) 172.172 g/mol (dihydrate) Appearance ... Calcium sulfate exists in three hydrates, a dihydrate, a hemihydrate and a anhydrous form. Over 100 degrees the hemihydrate …

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Effect of Soluble Phosphorus on the Mechanical …

hemihydrate gypsum, and the influence degree of different forms of soluble phosphorus is unclear. Therefore, the utilization of a-hemihydrate gypsum is greatly limited. In this study, the effect of soluble phosphorus on the setting time and mechanical properties of a-hemihydrate gypsum was investi-gated by adding different amounts of H 3PO 4 ...

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Crystallization Kinetics of α-Hemihydrate …

α-Calcium sulfate hemihydrate (α-HH) is an important cementitious material, which can be prepared by hydrothermal method from calcium sulfate dihydrate (DH) in an electrolyte solution. Study of the …

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Hemihydrate

Sustainability of gypsum products as a construction material. N. Lushnikova, L. Dvorkin, in Sustainability of Construction Materials (Second Edition), 2016 β-Hemihydrate binder. β-Hemihydrate (also known as plaster of Paris) is the most commonly used gypsum binder in construction.It is produced in an apparatus connected to air. Different equipment is …

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Gypsum vs. Plaster of Paris: What's the Difference?

Gypsum is a mineral (calcium sulfate dihydrate) used in construction; Plaster of Paris is a quick-setting gypsum product used in mold making and casting. Key Differences Gypsum, naturally occurring as a mineral, is widely used in the construction industry for drywall and plaster products.

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Thermal Analysis of Gypsum

transition from hemihydrate gypsum to crystalline gypsum (dihydrate gypsum). This brief presents examples of TG/DTA and DSC measurements of the thermal changes of …

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Revealing maleic acid role in the preparation of α-hemihydrate gypsum …

The applications of gypsum in China are primarily twofold: the preparation of high-strength gypsum, construction gypsum, composite cementing materials, and others, and the preparation of gypsum building products like gypsum board and gypsum blocks. Among these, α-hemihydrate gypsum (α-HH) is a high-end gypsum product, mainly …

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Anhydrite and gypsum

Anhydrite (CaSO 4) and gypsum (CaSO 4 ·2H 2 O) are the two most abundant minerals of ancient marine evaporite deposits and are also common in non-marine evaporite deposits. Sedimentary gypsum forms by direct precipitation out of evaporating seawater under arid climatic conditions in hydrologically restricted marine …

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Effect of Soluble Phosphorus on the Mechanical Properties …

Preparation of α-hemihydrate gypsum crystal is an approach for utilization of phosphogypsum (PG), but the soluble phosphorus impurities in PG have a crucial influence on the performance of α-hemihydrate gypsum. In this article, different forms of soluble phosphorus (H3PO4, H2PO4− and HPO42−) on the setting time and mechanical …

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Formation of α-Hemihydrate Inside of a Gypsum Crystal …

Gypsum (calcium sulfate dihydrate) is one of the most used inorganic binding materials in the world. During calcination, calcium sulfate subhydrates are formed and, for technical reasons, are ...

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Gypsum | Properties, Formation, Uses and …

Gypsum is a naturally occurring mineral that has been used by humans for various purposes for thousands of years. It is a versatile mineral with a wide range of applications in construction, agriculture, …

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Factsheet on: What is Gypsum?

When Gypsum (CaSO4,2H2O) is ground to a powder and heated at 150° to 165° C, three-quarters of its combined water is removed producing hemi-hydrate plaster …

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Coordinated disposal of FGD gypsum and power plant …

In Section 3.4, the industrial salt for exploring the optimal process parameters for preparing α-hemihydrate gypsum is the anhydrous form of calcium chloride and magnesium chloride. The cost is high. In actual production, magnesium chloride hexahydrate and calcium chloride dihydrate with lower prices are used as regulators for …

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Facile preparation of α-calcium sulfate hemihydrate whisker …

1. Introduction. Gypsum, an important mineral resource, is widely used in the chemical industry [1], agriculture [2], medical treatment [3], building materials [4], food [5], and other fields, which mainly come from natural and industrial by-products.In the field of chemical industry, gypsum is commonly used as a raw material for the production of …

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Gypsum Mineral | Uses and Properties

Gypsum is an evaporite mineral most commonly found in layered sedimentary deposits in association with halite, anhydrite, sulfur, calcite, and dolomite. Gypsum (CaSO 4. 2H 2 O) is very similar to Anhydrite …

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How can we estimate the quantity of gypsum (CaSO4 2H2O), hemihydrate

Since you determine the water amount, it would be easy to separate the corresponding hydrated phase, the difference would be associated with the anhydrous phase. Cite 2 Recommendations

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Materials | Free Full-Text | Experimental Study and …

Flue-gas desulphurization (FGD) gypsum is a highly prevalent industrial by-product worldwide, which can be an excellent alternative to natural gypsum due to its high content of CaSO4·2H2O. The preparation of α-calcium sulfate hemihydrate is a high-value pathway for the efficient use of FGD gypsum. Here, a dynamic method, or an improved …

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Preparation of α-calcium sulfate hemihydrate from …

gypsum, flue gas desulfurization (FGD) gypsum and phosphogypsum (PG) have the largest output. FGD gypsum originates from the flue gas desulfurization installations by sorption of SO 2 in power stations. For example, in the wet-lime desulfurization method, the sorption reaction occurs via the reaction formulas (1, 2) (Roszczynialski et al., 1996a).

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Crystallization and Phase Stability of CaSO4 and CaSO4

Calcium sulfate occurs in nature in form of three different minerals distinguished by the degree of hydration: gypsum (CaSO 4 ·2H 2 O), hemihydrate (CaSO 4 ·0.5H 2 O) and anhydrite (CaSO 4).On the one hand the conversion of these phases into each other takes place in nature and on the other hand it represents the basis of gypsum-based building …

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No. 4710 February 6, 1960 NATURE 375

thermal analysis in a sample of hemihydrate prepared by calcining gypsum under conditions simulating the manufacture of gypsum plaster in a kettle. By means of differential thermal analysis it is ...

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Preparation of hemihydrate gypsum with controllable …

DOI: 10.1016/j.jcrysgro.2021.126360 Corpus ID: 241731164; Preparation of hemihydrate gypsum with controllable morphology in Glycerol-NaCl-Water solutions with maleic acid @article{Chen2021PreparationOH, title={Preparation of hemihydrate gypsum with controllable morphology in Glycerol-NaCl-Water solutions with maleic acid}, …

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Dehydration Pathways of Gypsum and the Rehydration …

The dehydration products of gypsum under different temperature and water vapor pressure were investigated by thermodynamic theory. Additionally, the rehydration mechanism of soluble anhydrite was also studied by Monte Carlo (MC) simulations. The thermodynamic calculation results reveal that the dehydration mechanism of gypsum …

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